Trapping an unusual pentacoordinate carbon atom in a neutral trialuminum complex
dc.contributor.author | Nery Villegas-Escobar | |
dc.contributor.author | Javier Martínez | |
dc.contributor.author | Ricardo A. Matute | |
dc.contributor.author | Sebastián Saltarini | |
dc.contributor.author | Constantin G. Daniliuc | |
dc.contributor.author | Lutz H. Gade | |
dc.contributor.author | René S. Rojas | |
dc.date.accessioned | 2023-05-19T20:25:28Z | |
dc.date.available | 2023-05-19T20:25:28Z | |
dc.date.issued | 2021 | |
dc.description.abstract | A neutral trialuminum complex incorporates a pentacoordinate carbon through a methylidene bridge linking the three metal atoms. The rigid electron-deficient Al-3 core stabilizes the hypercoordinate carbon atom resulting in the shortest equatorial Al-C distance reported for such an Al-3-(mu(3)-CH2) unit. | |
dc.fuente.origen | ORCID-mayo23 | |
dc.identifier.doi | 10.1039/D1CC04265C | |
dc.identifier.uri | https://repositorio.uc.cl/handle/11534/67409 | |
dc.language.iso | en | |
dc.title | Trapping an unusual pentacoordinate carbon atom in a neutral trialuminum complex | es_ES |
dc.type | artículo |