Monomer reactivity in functionalized vinyl copolymers: A theoretical approach

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dc.contributor.authorGatica, N
dc.contributor.authorGargallo, L
dc.contributor.authorRadic, D
dc.date.accessioned2024-01-10T13:15:09Z
dc.date.available2024-01-10T13:15:09Z
dc.date.issued2004
dc.description.abstractThis work studies how the variation of the inter-atomic distance affects the total energy in addition reactions of several vinyl radicals on vinyl monomers. Based on the energetic profiles obtained, the corresponding activation eneigies were evaluated and correlated with the relative reactivity of the monomers forming the vinyl copolymers poly(2-vinylpyridine-co-N-vinyl-2-pyrrolidone), poly(4-vinylpyridine-co-N-vinyl-2-pyrrolidone), poly(vinyltrimethylsilane-co-N-vinyl-2-pyrrolidone) and poly(vinylcyclohexane-co-N-vinyl-2-pyrrolidone), previously characterized with an estimation of their monomer reactivity ratios (MRR). The results are discussed as a theoretical support to a work developed in the general framework of the synthesis and characterization of functionalized vinyl copolymers.
dc.fechaingreso.objetodigital2024-05-09
dc.format.extent8 páginas
dc.fuente.origenWOS
dc.identifier.doi10.1081/MA-120027302
dc.identifier.issn1060-1325
dc.identifier.urihttps://doi.org/10.1081/MA-120027302
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/78476
dc.identifier.wosidWOS:000189154900006
dc.information.autorucQuímica;Gargallo L;S/I;98194
dc.information.autorucQuímica;Radic D;S/I;49367
dc.issue.numero2
dc.language.isoen
dc.nota.accesocontenido parcial
dc.pagina.final188
dc.pagina.inicio181
dc.publisherMARCEL DEKKER INC
dc.revistaJOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
dc.rightsacceso restringido
dc.subjectmonomer reactivity ratios
dc.subjectaddition reactions
dc.subjectactivation energy
dc.subjectfunctionalized vinyl copolymers
dc.subjectRATIOS
dc.titleMonomer reactivity in functionalized vinyl copolymers: A theoretical approach
dc.typeartículo
dc.volumen41
sipa.codpersvinculados98194
sipa.codpersvinculados49367
sipa.indexWOS
sipa.trazabilidadCarga SIPA;09-01-2024
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