Synthesis of 2H-naphtho[2,3-b]thiopyranoquinones and density functional study for the Diels-Alder reaction of a benzothiopyranoquinone

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Synthesis of 2H-naphtho[2,3-b]thiopyranoquinones and density functional study for the Diels-Alder reaction of a benzothiopyranoquinone.pdf(486.44 KB)
Date
2000
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PERGAMON-ELSEVIER SCIENCE LTD
Abstract
The synthesis of benzothiopyranoquinone (6) in three step from benzothiopyran (3) is described. Diels-Alder reaction of quinone (6) with 1,3-pentadiene (7), cyclopentadiene, 1-methoxy-1,3-cyclohexadiene (11) and 1-dimethylamino-1-aza-1,3-pentadiene (14) was studied. The Density Functional Theory was applied to explain the orientation of the cycloaddition reaction of quinone (6) with dienes (7), (11) and (14).
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MAXIMUM HARDNESS, SULFUR ANALOGS, PRINCIPLE, NAPHTHO<2,3-B>PYRANOQUINONES, REGIOSELECTIVITY, NAPHTHOQUINONES, INTERMEDIATE
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https://repositorio.uc.cl/handle/11534/79789
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