Rhodium(I) diolefin complexes with polycyclic π-arene ligands. Synthesis of bimetallic complexes with diphenylmethane as bridging ligand

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dc.contributor.authorValderrama Guerrero, Mauricio
dc.contributor.authorScotti Radich, Mario
dc.contributor.authorCifuentes, Pedro
dc.contributor.authorGanz, Ricardo
dc.date.accessioned2019-12-28T02:45:29Z
dc.date.available2019-12-28T02:45:29Z
dc.date.issued1984
dc.description.abstractThe preparation and properties of cationic arenerhodium(I) complexes of general formula [Rh(diolefin)(?6arene)]ClO4 (diolefin=1,5-cyclooctadiene, tetrafluorobenzobarrelene or trimethyltetrafluorobenzobarrelene; arene = biphenyl or diphenylmethane) are described. These complexes react with the solvated intermediate complex [Rh(diolefin)(Me2CO)x]ClO4 to give homobimetallic [(diolefin)Rh(Ph2CH2)Rh(diolefin)](ClO4)2 derivatives. New heterobimetallic complexes of the type [(diolefin)Rh(Ph2CH2)Cr(CO)3]ClO4 have been synthesized by reaction of Cr(CO)3(?6-Ph2CH2) with the solvated complex [Rh(diolefin)(Me2CO)x]ClO4 or, alternatively by treatment of [Rh(diolefin)(?6-arene)]ClO4 with the complex Cr(CO)3(?6Me3B3N3Me3) in chloroform solution.
dc.fuente.origenSpringer
dc.identifier.doi10.1007/BF00618172
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/27131
dc.identifier.urihttp://link.springer.com/article/10.1007/BF00618172
dc.issue.numeroNo. 8
dc.language.isoen
dc.nota.accesoContenido parcial
dc.revistaTransition Metal Chemistryes_ES
dc.rightsacceso restringido
dc.subject.ddc510
dc.subject.deweyMatemática física y químicaes_ES
dc.subject.otherQuimica fisicaes_ES
dc.subject.otherQuímica inorgánicaes_ES
dc.subject.otherCloroformoes_ES
dc.titleRhodium(I) diolefin complexes with polycyclic π-arene ligands. Synthesis of bimetallic complexes with diphenylmethane as bridging ligandes_ES
dc.typeartículo
dc.volumenVol. 9
sipa.codpersvinculados98352
sipa.codpersvinculados59615
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