Spontaneous Adsorption of Gold Nanoparticles by Polyelectrolyte Thin Films

dc.contributor.authorUrzua, Marcela
dc.contributor.authorLeiva, Angel
dc.contributor.authorEspinoza Beltran, Francisco J.
dc.contributor.authorBriones, Ximena
dc.contributor.authorSaldias, Cesar
dc.contributor.authorPino, Maximiliano
dc.date.accessioned2024-01-10T12:08:46Z
dc.date.available2024-01-10T12:08:46Z
dc.date.issued2012
dc.description.abstractNanocomposed films constituted by gold nanoparticles immobilized onto polyelectrolytes were obtained and studied. To obtain the films, amino terminated silicon wafer surfaces were put in contact with aqueous solution of polyelectrolytes derived from Poly(maleic anhydride-alt-styrene) containing aryl and amine-alkyl groups in the side chains, in this condition the adsorption of macromolecules was achieved. The effects of the chemical nature of the side chains and ionic strength on the amounts of adsorbed polyelectrolytes were studied by ellipsometry. The adsorption of polyelectrolytes increases with increasing ionic strength in agreement with the screening-enhanced adsorption regime; the results are discussed considering the steric hindrance of the side chains and flexibility of the polymers. A spontaneous adsorption process of nanoparticles onto polyelectrolyte films took place when these last were immersed in a gold nanoparticles suspension. The adsorption amounts were qualitatively evaluated by SEM and AFM and these showed to be dependent on chemical structure of polyelectrolytes.
dc.description.funderFondecyt
dc.fechaingreso.objetodigital2024-05-20
dc.format.extent9 páginas
dc.fuente.origenWOS
dc.identifier.doi10.1166/jnn.2012.6669
dc.identifier.eissn1533-4899
dc.identifier.issn1533-4880
dc.identifier.pubmedidMEDLINE:23421219
dc.identifier.urihttps://doi.org/10.1166/jnn.2012.6669
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/76426
dc.identifier.wosidWOS:000313851000020
dc.information.autorucQuímica;Leiva A;S/I;88381
dc.information.autorucQuímica;Pino M;S/I;125102
dc.information.autorucQuímica;Saldias C;S/I;125097
dc.issue.numero11
dc.language.isoen
dc.nota.accesocontenido parcial
dc.pagina.final8390
dc.pagina.inicio8382
dc.publisherAMER SCIENTIFIC PUBLISHERS
dc.revistaJOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
dc.rightsacceso restringido
dc.subjectNanocomposites
dc.subjectPolyelectrolyte Films
dc.subjectGold Nanoparticles
dc.subjectAdsorption
dc.subjectNANOCRYSTALS
dc.subjectPOLYMER
dc.subjectSIZE
dc.subjectCATALYSIS
dc.subjectBEHAVIOR
dc.subjectTRANSITION
dc.subjectREDUCTION
dc.subjectCOPOLYMER
dc.subject.ods03 Good Health and Well-being
dc.subject.odspa03 Salud y bienestar
dc.titleSpontaneous Adsorption of Gold Nanoparticles by Polyelectrolyte Thin Films
dc.typeartículo
dc.volumen12
sipa.codpersvinculados88381
sipa.codpersvinculados125102
sipa.codpersvinculados125097
sipa.indexWOS
sipa.indexScopus
sipa.trazabilidadCarga SIPA;09-01-2024
Files
Original bundle
Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
Spontaneous adsorption of gold nanoparticles by polyelectrolyte thin films.pdf
Size:
2.74 KB
Format:
Adobe Portable Document Format
Description: