Preparation and properties of cationic trimethylphosphiterhodium(I) complexes with arene ligands

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dc.contributor.authorValderrama Guerrero, Mauricio
dc.contributor.authorScotti Radich, Mario
dc.contributor.authorMeriggio, Flavia
dc.date.accessioned2019-12-28T02:45:24Z
dc.date.available2019-12-28T02:45:24Z
dc.date.issued1988
dc.description.abstractThe preparation and properties of cationic arenerhodium(I) complexes of general formula [Rh {P(OMe)3}(?6-arene)]A [arene=C6H6?nMen (n=0, 1, 2, 3, 4 or 6); A=ClO 6? , PF 6? ] are described. The coordinated arene is dissociated in (CD3)2 CO or DCCl3 solution and this dissociation decreases with increased methyl substitution of the arene ligand. The ability of these cationic complexes to function as an intermediate for the synthesis of other rhodium(I) complexes by displacement of the coordinated arene with ? or ?-donor ligands has been studied.The preparation and properties of cationic arenerhodium(I) complexes of general formula [Rh {P(OMe)3}(?6-arene)]A [arene=C6H6?nMen (n=0, 1, 2, 3, 4 or 6); A=ClO 6? , PF 6? ] are described. The coordinated arene is dissociated in (CD3)2 CO or DCCl3 solution and this dissociation decreases with increased methyl substitution of the arene ligand. The ability of these cationic complexes to function as an intermediate for the synthesis of other rhodium(I) complexes by displacement of the coordinated arene with ? or ?-donor ligands has been studied.
dc.fuente.origenSpringer
dc.identifier.doi10.1007/BF01041493
dc.identifier.urihttps://doi.org/10.1007/BF01041493
dc.identifier.urihttp://link.springer.com/article/10.1007/BF01041493
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/27112
dc.issue.numeroNo. 1
dc.language.isoen
dc.nota.accesoContenido parcial
dc.revistaTransition Metal Chemistryes_ES
dc.rightsacceso restringido
dc.subject.ddc510
dc.subject.deweyMatemática física y químicaes_ES
dc.subject.otherMetiloes_ES
dc.subject.otherCatálisises_ES
dc.subject.otherQuímica - Físicaes_ES
dc.subject.otherQuímica Inorgánicaes_ES
dc.titlePreparation and properties of cationic trimethylphosphiterhodium(I) complexes with arene ligandses_ES
dc.typeartículo
dc.volumenVol. 13
sipa.codpersvinculados98352
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