Synthesis and structure of some heterobimetallic complexes having a polyalkyl-s-indacenyl spacer
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Date
2013
Journal Title
Journal ISSN
Volume Title
Publisher
ELSEVIER SCIENCE SA
Abstract
Three heterobimetallic complexes LmM(s-Ic')M'Ln (M = Fe, Ru or Mn; M' = Ni) having the same Cp* nickel moiety and based on a polyalkyl-s-indacenyl spacer (s-Ic' = 2,6-diethyl-4,8-dimethyl-s-indacenyl) were synthesized by reacting Cp* Ni(acac) with the lithium derivative of the parent monometalated complex. All three compounds were fully characterized and shown to adopt a trans geometry by X-ray crystallography. (C) 2012 Elsevier B. V. All rights reserved.
Description
Keywords
Polyalkyl-s-indacene, Nikel indacenyl heterobimetallic complexes: Ni/Fe Ni/Ru, Ni/Mn, X-ray structures, Manganese s-indacenyl complex, TRIPLE-DECKER COMPLEXES, AS-INDACENE, ELECTRONIC COMMUNICATION, THERMAL REARRANGEMENT, PENTALENE COMPLEXES, IR(I) COMPLEXES, MIXED-VALENT, REACTIVITY, DERIVATIVES, ROUTE