Synthesis and structure of dicarbonyldichloro{2-(diphenylphosphineoxide)pyridine}ruthenium(II)
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Date
2008
Journal Title
Journal ISSN
Volume Title
Publisher
SOC CHILENA QUIMICA
Abstract
Reaction of the dinuclear complex [{Ru(CO)(3)Cl-2}(2)] with the ligand 2-(diphenylphosphineoxide)pyridine (PyPOPh2) in ethanol solution gave the neutral mononuclear complex [Ru(k(2)-PyPOPh2-N,O)(CO)(2)Cl-2]. The complex was characterized by elemental analysis, IR and RMN spectroscopy, and its molecular structure was determined by single-crystal X-ray diffraction.
Description
Keywords
ruthenium, 2-(diphenylphosphineoxide)pyridine complexes, dicarbonyl complexes, crystal structure, COMPLEXES, 2-(DIPHENYLPHOSPHINO)PYRIDINE, CHEMISTRY, LIGANDS