Synthesis and reactivity of cationic trimethyltetrafluorobenzobarrelene rhodium(I) complexes

Valderrama Guerrero, Mauricio; Ganz, Ricardo; Sariego, Renato

Synthesis and reactivity of cationic trimethyltetrafluorobenzobarrelene rhodium(I) complexes

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Synthesis and reactivity of cationic trimethyltetrafluorobenzobarrelene rhodium(I) complexes.pdf(111.29 KB)

Date

1983

Authors

Valderrama Guerrero, Mauricio

Ganz, Ricardo

Sariego, Renato

Abstract

The preparation and properties of cationic rhodium(I) complexes of the types [Rh(Me3TFB)L2]PF6 (L=O. N. P, As or Sb-donor ligands, Me3TFB=trimethyltetrafluorobarrelene), [Rh(Me3TFB) (?6-arene)]PF6 (arene=C6Me6, C6H6Me3, C6H6 or C10H8) and [Rh(Me23TFB)(PPh3)L]PF6 (L=Me2CO or Me2SO) are described. Some complexes react with carbon monoxide at normal pressure with displacement of Me3TFB and formation of carbonyl derivatives. The arene-exchange behaviour for the new complex with naphthalene (C10H8) was examined in acetone solutions.

URI

https://repositorio.uc.cl/handle/11534/27113
http://link.springer.com/article/10.1007/BF00956025

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