Catalytic activity and visible spectroscopy of [Rh(norbornadiene)Cl]2/p-RC6H4)3P system in methanol

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dc.contributor.authorSantos, José G.
dc.date.accessioned2019-12-28T02:45:18Z
dc.date.available2019-12-28T02:45:18Z
dc.date.issued1984
dc.description.abstractThe catalytic hydrogenation of hex-1-ene in methanolic solution with [Rh(norbornadiene)Cl]2/(p-RC6H4)3 P (R=H, Me or OMe) systems preparedin situ has been measured. The catalytic activity shows a dependence on the ageing of the catalyst precursor solution in the presence of air. A spectroscopic study (visible region) has been carried out for the system with triphenyl phosphine and shows degradation with the formation of [Rh(norbornadiene)PPh3Cl] as an intermediate. It was demonstrated that the spectral changes and the consequent catalytic activity are due to PPh3 loss because of the oxygen dissolved in the media.
dc.format.extent2
dc.fuente.origenSpringer
dc.identifier.doi10.1007/BF00935933
dc.identifier.urihttps://doi.org/10.1007/BF00935933
dc.identifier.urihttps://repositorio.uc.cl/handle/11534/27092
dc.issue.numeroNo. 4
dc.pagina.final157
dc.pagina.inicio155
dc.revistaTransition Metal Chemistryes_ES
dc.subjectOxygenes_ES
dc.subjectHydrogenationes_ES
dc.subjectSpectroscopyes_ES
dc.subjectMethanoles_ES
dc.subjectCatalysises_ES
dc.subject.ddc510
dc.subject.deweyMatemática física y químicaes_ES
dc.titleCatalytic activity and visible spectroscopy of [Rh(norbornadiene)Cl]2/p-RC6H4)3P system in methanoles_ES
dc.typeartículo
dc.volumenVol. 9
sipa.codpersvinculados98813
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