Browsing by Author "René S. Rojas"
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- ItemStannylenes and Germylenes Stabilized by Tetradentate Bis(amidine) Ligands with a Rigid Naphthalene Backbone(2024) Alejandra Acuña; Sonia Mallet-Ladeira; Jean-Marc Sotiropoulos; Eddy Maerten; Cabrera Caballero, Alan Raul; Antoine Baceiredo; Tsuyoshi Kato; René S. Rojas; David Madec
- ItemTrapping an unusual pentacoordinate carbon atom in a neutral trialuminum complex(2021) Nery Villegas-Escobar; Javier Martínez; Ricardo A. Matute; Sebastián Saltarini; Constantin G. Daniliuc; Lutz H. Gade; René S. RojasA neutral trialuminum complex incorporates a pentacoordinate carbon through a methylidene bridge linking the three metal atoms. The rigid electron-deficient Al-3 core stabilizes the hypercoordinate carbon atom resulting in the shortest equatorial Al-C distance reported for such an Al-3-(mu(3)-CH2) unit.