Browsing by Author "Garcia, Veronica"

Now showing 1 - 2 of 2
  • No Thumbnail Available
    Item
    Assessment of contaminants of emerging concern and antibiotic resistance genes in the Mapocho River (Chile): A comprehensive study on water quality and municipal wastewater impact
    (2024) Herrera-Munoz, Jose; Ibanez, Maria; Calzadilla, Wendy; Cabrera-Reina, Alejandro; Garcia, Veronica; Salazar-Gonzalez, Ricardo; Hernandez, Felix; Campos-Manas, Marina; Miralles-Cuevas, Sara
    The primary objective of this study was to evaluate the persistence and elimination of Contaminants of Emerging Concern (CECs) in municipal wastewater treatment plants (MWWTPs) and their presence in the Mapocho River within the metropolitan area of Santiago, Chile. The use of advanced analytical techniques, based on liquid chromatography coupled to both low and high-resolution mass spectrometry, allowed a comprehensive overview on the presence of CECs in samples. Additionally, a preliminary assessment of the microbiological aspects aimed to determine the presence of indicator microorganisms of fecal contamination, such as Escherichia coli and total coliforms was conducted. Furthermore, a qualitative assessment of Antibiotic Resistant Genes (ARGs) was performed. No CECs were detected upstream to the MWWTPs. However, the results from various wastewater samples (influent, secondary, and tertiary effluents) revealed significant diversity, with 73 CECs detected alongside prevalent ARGs including sult, , sulftt, , qnrB, , and blaTEM. . The presence of CECs and ARGs downstream of the MWWTP in the Mapocho River was mainly attributed to effluent discharge. On the other hand, typical values for a healthy river and a MWWTP with a final disinfection stage were found in terms of fecal contamination. Consequently, the imperative for developing tertiary or quaternary treatments capable of degrading CECs and ARGs to minimize environmental impact is underscored. These findings hold public health significance, offering insights into potential risks and influencing future legislative measures in Chile.
  • No Thumbnail Available
    Item
    Enhancing industrial swine slaughterhouse wastewater treatment: Optimization of electrocoagulation technique and operating mode
    (2024) Sandoval, Miguel A.; Coreno, Oscar; Garcia, Veronica; Salazar-Gonzalez, Ricardo
    In this study, industrial swine slaughterhouse effluents were treated by an electrocoagulation process (EC) with aluminum and iron electrodes. Batch and semicontinuous operation were performed. EC tests were carried out in batch operating mode for 2.5 h using fixed current densities (j = 10, 20, and 30 mA cm-2) in sulfate and chloride media. At the laboratory scale, higher TOC removal efficiencies were observed using aluminum electrodes at 20 mA cm-2 without the addition of a supporting electrolyte (82.7%). However, the EC process with Fe electrodes consumed 43.6% less energy.After the best operating parameters were found at the laboratory scale, the process was tested as a semi -continuous prepilot process using a filter-press FM01-LC-type electrochemical reactor equipped with flat plate aluminum electrodes. In this stage, current densities and mean linear flow rates were assessed. The highest TOC removal efficiency of 72.7% (i.e., residual TOC concentration of 85.18 mg L-1) in the semicontinuous process was achieved by the application of j = 25 mA cm-2 and ur = 0.64 cm s- 1 with an energy consumption of 19.80 kW h m- 3. The residual COD and TP concentrations met the international standard limits. Moreover, complete decoloration and disinfection were accomplished. EDXRF, SEM, EDAX, XRD, and FTIR analyses indicated that pollutants were removed by adsorption on aluminum/iron hydroxides/oxyhydroxides.